Dr Jörgen Rosenqvist
Research Fellow
Telephone number:
+44(0) 113 34
35543
Email address: J.Rosenqvist@leeds.ac.uk
Room: 8.151
Biography
- 2009 - present: Research fellow, Leeds University
- 2005 - 2009: Post doctoral associate, Oak Ridge National Laboratory, Oak Ridge TN, USA
- 2002 - 2005: Post doctoral associate, University of California, Davis CA, USA
- 2002: PhD in chemistry, Umeå University, Sweden
In my research I study the interactions between minerals and (aqueous) fluids, with an emphasis on understanding the structure and dynamics of the interfacial region. To this end I have used a host of different techniques to obtain information on both the molecular level and the macroscopic level.
I'm also interested in developing surface complexation models that are consistent with data on both levels.
Currently I'm affiliated with Carbon Research into Underground Storage (CRIUS), a NERC funded consortium concerned with predicting the fate of CO2 in geological reservoirs. Within this framework we strive to understand the fate of CO2 after injection into storage reservoirs, in particular to evaluate the extent to which it will dissolve into formation waters (solubility trapping) or precipitate as minerals (mineral trapping). We perform laboratory experiments to determine the extent and the rate of reactions between reservoir minerals and formation fluids and compare the obtained results to results from theoretical calculations. The experimental work is performed in the Cohen Laboratory in Leeds.
Qualifications
MSc in Chemical Engineering, Åbo Akademi , Turku, Finland.
PhD in Chemistry, Umeå University, Umeå, Sweden
Memberships/Fellowships
Member of the Geochemical Society, the American Chemical Society
Research Interests
Mineral-fluid interaction, carbon sequestration, chemical speciation, surface complexation modelling
Publications
- Rosenqvist J; Kilpatrick AD; Yardley BWD (2012) Solubility of carbon dioxide in aqueous fluids and mineral suspensions at 294 K and subcritical pressures, Applied Geochemistry, .
- Wesolowski DJ; Sofo JO; Bandura AV; Zhang Z; Mamontov E; Předota M; Kumar N; Kubicki JD; Kent PRC; Vlcek L; MacHesky ML; Fenter PA; Cummings PT; Anovitz LM; Skelton AA; Rosenqvist J (2012) Comment on "structure and dynamics of liquid water on rutile TiO 2(110)", Physical Review B - Condensed Matter and Materials Physics, 85, .
- Machesky M; Wesolowski D; Rosenqvist J; Predota M; Vlcek L; Ridley M; Kohli V; Hang Z; Fenter P; Cummings PT; Lvov S; Fedkin M; Rodriguez-Santiago V; Kubicki J; Bandura A (2011) Comparison of Cation Adsorption by Isostructural Rutile and Cassiterite, LANGMUIR, 27, pp.4585-4593. doi: 10.1021/la1040163
- Davis MC; Wesolowski DJ; Rosenqvist J; Brantley SL; Mueller KT (2011) Solubility and near-equilibrium dissolution rates of quartz in dilute NaCl solutions at 398-473 K under alkaline conditions, GEOCHIMICA ET COSMOCHIMICA ACTA, 75, pp.401-415. doi: 10.1016/j.gca.2010.10.023
- Wang P; Wilson LL; Wesolowski DJ; Rosenqvist J; Anderko A (2010) Solution chemistry of Mo(III) and Mo(IV): Thermodynamic foundation for modeling localized corrosion, CORROSION SCIENCE, 52, pp.1625-1634. doi: 10.1016/j.corsci.2010.01.032
- Mamontov E; Vlcek L; Wesolowski DJ; Cummings PT; Rosenqvist J; Wang W; Cole DR; Anovitz LM; Gasparovic G (2009) Suppression of the dynamic transition in surface water at low hydration levels: A study of water on rutile, PHYSICAL REVIEW E, 79, . doi: 10.1103/PhysRevE.79.051504
- Rodriguez-Santiago V; Fedkin MV; Wesolowski DJ; Rosenqvist J; Lvov SN (2009) Electrophoretic Study of the SnO2/Aqueous Solution Interface up to 260 degrees C, LANGMUIR, 25, pp.8101-8110. doi: 10.1021/la900611u
- Rosenqvist J; Machesky ML; Vlcek L; Cummings PT; Wesolowski DJ (2009) Charging Properties of Cassiterite (alpha-SnO2) Surfaces in NaCl and RbCl Ionic Media, LANGMUIR, 25, pp.10852-10861. doi: 10.1021/la901396w
- Machesky ML; Predota M; Wesolowski DJ; Vlcek L; Cummings PT; Rosenqvist J; Ridley MK; Kubicki JD; Bandura AV; Kumar N; Sofo JO (2008) Surface Protonation at the Rutile (110) Interface: Explicit Incorporation of Solvation Structure within the Refined MUSIC Model Framework, LANGMUIR, 24, pp.12331-12339. doi: 10.1021/la801356m
- Machesky ML; Wesolowski DJ; Ridley MK; Palmer DA; Rosenqvist J; Lvov SN; Fedkin M; Pf edota M; Vlcek L (2008) The protonation behavior of metal oxide surfaces to hydrothermal conditions, ECS Transactions, 11, pp.151-166.
- Mamontov E; Wesolowski DJ; Vlcek L; Cummings PT; Rosenqvist J; Wang W; Cole DR (2008) Dynamics of hydration water on rutile studied by backscattering neutron spectroscopy and molecular dynamics simulation, JOURNAL OF PHYSICAL CHEMISTRY C, 112, pp.12334-12341. doi: 10.1021/jp711965x
- Vlcek L; Zhang Z; Machesky ML; Fenter P; Rosenqvist J; Wesolowski DJ; Anovitz LM; Predota M; Cummings PT (2007) Electric double layer at metal oxide surfaces: Static properties of the cassiterite - Water interface, LANGMUIR, 23, pp.4925-4937. doi: 10.1021/la063306d
- Mamontov E; Vlcek L; Wesolowski DJ; Cummings PT; Wang W; Anovitz LM; Rosenqvist J; Brown CM; Sakai VG (2007) Dynamics and structure of hydration water on rutile and cassiterite nanopowders studied by quasielastic neutron scattering and molecular dynamics simulations, JOURNAL OF PHYSICAL CHEMISTRY C, 111, pp.4328-4341. doi: 10.1021/jp067242r
- Swaddle TW; Rosenqvist J; Yu P; Bylaska E; Philiips BL; Casey WH (2005) Kinetic evidence for five-coordination in AlOH(aq)(2+) ion, SCIENCE, 308, pp.1450-1453. doi: 10.1126/science.1110231
- Loring JS; Rosenqvist J; Casey WH (2004) Broad reactivity trends for oxygen-isotope exchange from the near-surface regions of some metal (hydr)oxide solids, JOURNAL OF COLLOID AND INTERFACE SCIENCE, 274, pp.142-149. doi: 10.1016/j.jcis.2003.09.041
- Shchukarev A; Rosenqvist J; Sjoberg S (2004) XPS study of the silica-water interface, JOURNAL OF ELECTRON SPECTROSCOPY AND RELATED PHENOMENA, 137, pp.171-176. doi: 10.1016/j.elspec.2004.02.095
- Rosenqvist J; Casey WH (2004) The flux of oxygen from the basal surface of gibbsite (alpha-Al(OH)(3)) at equilibrium, GEOCHIMICA ET COSMOCHIMICA ACTA, 68, pp.3547-3555. doi: 10.1016/j.gca.2004.02.022
- Rosenqvist J; Axe K; Sjoberg S; Persson P (2003) Adsorption of dicarboxylates on nano-sized gibbsite particles: effects of ligand structure on bonding mechanisms, COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 220, pp.91-104. doi: 10.1016/S0927-7757(03)00063-3
- Rosenqvist J; Persson P; Sjoberg S (2002) Protonation and charging of nanosized gibbsite (alpha-Al(OH)(3)) particles in aqueous suspension, LANGMUIR, 18, pp.4598-4604. doi: 10.1021/la015753t
- Persson P; Nordin J; Rosenqvist J; Lovgren L; Ohman LO; Sjoberg S (1998) Comparison of the adsorption of o-phthalate on boehmite (gamma-AlOOH), aged gamma-Al2O3, and goethite (alpha-FeOOH), JOURNAL OF COLLOID AND INTERFACE SCIENCE, 206, pp.252-266. doi: 10.1006/jcis.1998.5668
- ANDERSSON O; ROSENQVIST J; KARLSSON K (1993) DISSOLUTION, LEACHING, AND AL2O3 ENRICHMENT AT THE SURFACE OF BIOACTIVE GLASSES STUDIED BY SOLUTION ANALYSIS, JOURNAL OF BIOMEDICAL MATERIALS RESEARCH, 27, pp.941-948. doi: 10.1002/jbm.820270713